Hydroformylation process and catalyst

ABSTRACT

1. IN A HYDROFORMYLATION PROCESS IN WHICH AN OLEFIN IS REACTED WITH CARBON MONOXIDE AND HYDROGEN UNDER HYDROFORMYLATION CONDITIONS; THE IMPROVEMENT WHICH COMPRISES CARYING OUT THE REACTION UNDER HYDROFORMYLATION CONDITIONS IN THE PRESENCE OF A CATALYST PRODUCED BY CONTACTING A SOLID PHOSPHORUS-CONTAINING POLYMER OF AT LEAST ONE PHOSPHINE OF THE FORMULA   ((R&#39;&#39;)2-P-),(R(5-N)-),(H2C=CH)N-BENZENE   WHEREIN EACH R IS HYDROGEN OR AN ALKYL GROUP HAVING 1 TO 4 CARBON ATOMS, THE TOTAL NUMBER OF CARBON ATOMS IN ALL OF THE R SUBSTITUENTS BEING 12 OR LESS, EACH R&#39;&#39; IS A HYDROCARBYL RADICAL SELECTED FROM THE ALKYL, CYCLOALKYL, ARYL AND COMBINATIONS THEREOF, SAID HYDROCARBYL RADICAL CONTAINING 1 TO 20 CARBON ATOMS, AND N IS 1 TO 3, WITH AT LEAST ONE METAL CARBONYL OF THE GROUP CONSISTING OF COBALT, RHODIUM, RUTHENIUM, PLATINUM AND PALLADIUM, SAID METAL BEING PRESENT IN AN AMOUNT IN THE RANGE OF 0.2 TO 20 MILLIMOLE OF METAL PER 5 GRAMS OF POLYMER SUPPORT.

% TRANSMITTANCE Npv. 12, 1974 J. D. ALLEN 3,847,997

HYDROFORMYLATION PROCESS AND CATALYST Filed June 12, 1969 0 I I I I I I l I I I I 3 4 5 e 7 a 9 IO WAVELENGTH (mlcRoNs) FIG. 2

PRODUCT f 14 ls cofl 2 l3 HEM INVENTOR. J.D.ALLEN oLEF|N BY I" Q F/ G. I is ISIS A TTORNEYS United States Paten 3,847,997 HYDROFORMYLATION PROCESS AND CATALYST James D. Allen, Bartlesville, kla., assiguor to j Phillips Petroleum Company Filed June 12, 1969, Ser. No. 832,729 Int. Cl. C07c 45/08, 45/10 US. Cl. 260-604 HF 12 Claims ABSTRACT OF THE DISCLOSURE 'Hydroformylation reactions are carried out inthe presence of a catalyst comprising a solid polymer of a trivalent phosphorus-containing compound having associated therewith a metal of the group cobalt, rhodium, ruthenium, platinum and palladium. The polymer, which can be formed in part of a polyvinylaromatic compound, can be used to remove catalyst residues from hydroformylation reaction efiluent streams. In addition, p-styryldiethylphosphine and a polymer thereof are new compositions'of matter.

It is well known that various olefins can be reacted with carbon monoxide and hydrogen so as to be converted into corresponding aldehydes and/or alcohols. These reactions are often referred to as oxo or hydroformy'lation reactions. In the past, dicobalt octacarbonyl has commonly been used as a catalyst for carrying out reactions of this type. A typical known reaction is one in which the catalyst comprises dissolved cobalt in a concentration of approximately 2,000 parts per million in the reaction zone. Unfortunately, substantial amounts of the catalyst are dissolved in the reaction products and must eventually be recovered. The recovery of catalyst from the reaction products is a relatively expensive operation and greatly increases the cost of the process. It is also known that reactions of this type can be carried out by use of catalyst systems which comprise a complex of a metal, such' as cobalt, and a phosphorus-containing ligand, see US.

Pats. 3,168,553, 3,239,566, 3,239,571 3,290,379 [and removal "is still 3,369,050, for example. However catalyst a problem in these systems.

In accordance with the present invention, an improved catalyst system is provided for use in oxo reactions. This is accomplished by combining conventional oxo catalysts,

such as dicobalt octacarbonyl, with a solid support formed of a trivalent phosphorus-containing polymer. B'y use of] a catalyst system of this type, it is possible tomaintain the concentration of metal in the reaction zone at a relatively low level. This greatly simplifies the removal of recovering catalyst residues from the reaction products tem in an oxo process.

In the drawing, FIG. 1 is a schematic representation of apparatus which can be employed to carry out the process,

of this invention. FIG. 2 illustrates the infraredabsorpcatalyst residues from the reactlon products In addition,

a system is provided in accordance with this inventionfor f The novel catalyst system of this invention is formed by contacting a solid trivalent phosphorus-containing poly mer with a material which serves to promote the read-,1

tion of olefinic materials with carbon monoxide and hydfo gen. The materials which can be so employed are cobalt,

rhodium, ruthenium, platinum and/or palladium, which are in such a form as to constitute a metal carbonyl under the reaction conditions. In general, cobalt is the pre- 3,847,997 Patented Nov. 12, 1974 ferred metal, and advantageously can be in the form of cobalt hydrocarbonyl or dicobalt octacarbonyl.

The. phosphorus-containing polymers employed in the catalyst system of this invention are polymers of olefinically unsaturated phosphines having the formula:

wherein each R is hydrogen or an alkyl group containing 1 to 4 carbon atoms, the total number of carbon atoms in all of the R substituents in each molecule not exceeding 12; each R is a hydrocarbyl radical selected from the group consisting of alkyl, cycloalkyl, and aryl, and combinations thereof such as alkaryl, aralkyl, and the like,

saidhydrocarbyl radical containing 1 to 20 carbon atoms; and n is 1 to 3. Examples of such olefinically unsaturated phosphines which can be used as monomers include ostyryldimethylphosphine, p styryldiethylphosphine, mstyryldiisopropylphosphine, o styryldihexylphosphine, mstyrylmethylphenylphosphine, p styryldiphenylphosphine, 0 styryldibenzylphosphine, m styryl-p-tolylphosphine, p-styryldicyclohexylphosphine, 2,4 divinylphenyldidecylphosphine, 2,3,5 trivinylphenylbis(3 methylcyclopentyl)phosphine, 2 methyl 4 vinylphenylbis(cycloheptylmethyl)phosphine, 2 ethyl 4 isopropyl 6- vinylphenylbis(2 ethylhexyl)phosphine, 2,4,6 tributyl- 3,5 divinylphenyldieicosylphosphine, and the like, and mixtures thereof. When n in the above formula for the olefinically unsaturated phosphine is 2 or 3, the phosphine can be polymerized to a solid, cross-linked homopolymer, containnig phosphorus in trivalent form, useful inthe process of this invention. Particularly good results are obtained by use of a copolymer produced by polymerizing' at least one of the olefinically unsaturated phosphines represented by the above formula with about 1 to 40 parts by weight, per parts by weight of unsaturated phosphine, of a vinyl aromatic hydrocarbon. The vinylaromatic hydrocarbon so employed can have any one of the following general formulas:

( 1 11 (6n) T :1 R(gwherein each R and each n are as defined above. The substituents in the above Formulas (b) and (c) can be on either or both rings. Either the olefinically unsaturated phosphine or the vinyl aromatic hydrocarbon, or both,

styr'ene, 2-ethylstyrene, 1,2-divinylbenzene, 1,3-divinylbenzene, 1,4-divinylbenzene, 1,2,4-trivinylbenzene, 1,3-divinylnaphthalene, 1,8-divinylnaphthalene, 1,3,5-trivinylnaphthalene, 2,4-divinylbiphenyl, 3,4',5 trivinylbiphenyl, 1;2 divinyl 3,4-dimethylbenzene, 1,5,6-trivinyl-3,7-diethy1- naphthalcne, l,3-divinyl-4,5,8 tributylnaphthalene, 2,2-

divinyl 4-ethyl-4'-propylbiphenyl, 2,4,4'-trivinyl 2',3,3'- tributylbiphenyl, and the like, and mixtures thereof. The divinyl'aromatic hydrocarbons are preferred, particularly the isomeric divinylbenzenes. Commercial divinylbenzene,

-'which'comprises a mixture of the isomeric ortho, meta,

and para isomers, is quite suitable.

under a variety of reaction conditions. For example, re-

action temperatures in the general range of 25 to 150 are suitable. Although reaction pressures up to 100 p.s.i.g. or higher can be used, pressures near atmospheric are usually preferred. Reaction times are generally inthe range of 15 minutes to 150 hours. Although the polymerization can be carried out in the absence of a catalyst, ultraviolet light or catalysts such as 2,2'-azobis(2-methyl: propionitrile) can be employed to promote the polymerization. Preferably, a solvent is used, e.g., an aromatic hydrocarbon such as benzene, toluene, or xylene or a saturated hydrocarbon such as hexane, octane, cyclohexane, or methylcyclopentane. It is desirable that the polymerization be carried out in an inert atmosphere such as nitrogen to prevent oxidation of the phosphine or polymer thereof.

The catalyst system of this invention can be formed by any convenient procedure. For example, cobalt naphthe nate, dicobalt octacarbonyl, or other hydrocarbon-solublev compound or compounds of cobalt, rhodium, ruthenium, platinum, and/or palladium can be dissolved in an aromatic, paraffinic, or cycloparaffinic material or in the olefinic substance itself which is to be employed in theloxo.

reaction. The resulting solution can then be placed in contact with the polymer under an atmosphere of carbon monoxide and hydrogen at a temperature in the general range of 200-450" F. The mixture can be agitated until equilibrium has been attained between the metal on the polymer and metal in solution. This usually requires from about 10 seconds to about 1 hour. However, the catalyst system can actually be formed in the reaction chamber itself. The amount of metal on the polymer support is of the order of 0.04 to 4, preferably 0.1 to 2, millimoles of metal per gram of polymer support.

The oxo reaction is carried out by contacting an olefinic substance with carbon monoxide and hydrogen in,

the presence of the catalyst system of this invention. The reaction is generally carried out at pressures, under operating conditions, in the range of 600 to 5000 p.s.i.gL of' hydrogen and carbon monoxide, with about 15 -3500 p.s.i.g. being preferred. In general, alcohol production increases at higher pressures. The reaction temperature de' pends in part on the pressure employed and the reaction products desired. Temperatures generally are in the range Cyclic compounds, particularly hydrocarbons having or 6 carbon atoms in a ring structure, can be'reactedJThe" process of this invention is also applicable to"the'reaction of non-hydrocarbons containing ethylenic carbon-to-carvention can be employed to advantage in carrying out the various hydroformylation reactions enumerated in UiS.

Pat. 3,231,621.

In carrying out the process of this inventiom'at least: 1

mole of carbon monoxide and 2 moles of hydrogen are required for each mole of olefinic substance when alcohols are to be produced. In the production of aldehyde s, the hydrogen requirement is only half as great as' in alcohol 470' bon monoxide can be varied, depending in'p'art on the,v

production. Although the mole ratio of hydrogen to car? of about 200 to 450 F., preferably 3'00400F. The" bon linkages. In general, the catalyst system oft;his "in-f products desired, this mole ratio generally will be atileast 1. In some instances, the rate of reaction aswell as the 3 yield of desired products can be increased by increasing the mole ratio of hydrogen to carbon monoxide above 1% The catalyst system of this invention is quite effective in carrying out oxo reactions with commercially available feed streams containing sulfur compounds, which are considered to be catalyst poisons in conventional oxo reactions. It is believed that the polymer portion of the catalyst system may act as a reservoir for the soluble metal, and release additional metal to replace that which may be tied up by the catalyst poisons.

As previously mentioned, the solid polymer employed in preparing the catalyst system of this invention can also be used to advantage to remove catalyst residues from the reaction products. A system for carrying out the process of this invention, including catalyst residue removal, is illustrated schematically in FIG. 1 of the accompanying drawing. The apparatus therein illustrated comprises two chambers 10 and 11' which can be any suitable vessels of configurations capable of retaining the solid polymer of the catalyst system of this invention. For example, these chambers can be provided with screens at the two ends to retain the catalyst. It will be assumed that reactor 10 initially contains the complete catalyst system, whereas re actor '11 initially contains only the solid polymer component of the catalyst system. Olefinic feed, hydrogen and carbon monoxide are introduced through respective con- 1 duits 12, 13 and 14 which communicate with a common inlet conduit 15. Conduits 12, 13 and 14 can be provided with flow control means, not shown, to regulate the rates of introduction of the feed materials. A conduit 16, having a valve 17 therein, communicates between conduit 15 and a first inlet of reactor 10. A corresponding conduit 18, having a valve 19 therein, communicates between conduit 15 and reactor 11. A conduit 20, having a valve 21 therein, communicates between an outlet of reactor 10 and a common outlet conduit 22. A similar conduit 23, having a valve 24 therein, communicates between reactor 11 and conduit 22. A second inlet of reactor 10 is connectedto a second outlet thereof by conduits 26, 27 and 28, Valves 29 and 30 are disposed in respective conduits 26 and 28. Similarly, a second inlet of reactor 11 is connected to; a second outlet thereof by conduits 31, 27 and 32. Valves 33 and 34 are disposed in respective conduits 3 1 and 32.

At the beginning of the reaction cycle, valves 17, 30, 33 and 24 are open andvalves 19, 34, 29 and 21 are closed. Thus, the feed materials flow from conduit 15 through conduit 16, reactor 10,conduits 28, 27 and 31, reactor 11 and conduit. 23 to outlet conduit 22. The 0x0 reaction takes place in reactor 10, and the effluent stream passes through reactor 11. The polymer contained within chamber 11 serves to remove catalyst residues from the reaction products. cobalt, or other metal catalyst, which may be eiitraillfi? in the reactor eflluent, is deposited on the solid polymer in reactor 11 and is thereby removed from the effluent stream. This operation continues until the polymer in reactor 11 is no longer capable of removing the desired quantity, of catalyst residue and/ or until the catalyst in reactor 10 ha'slost its desired activity because of the removal of metal with thereactor efiluent stream. At this time, the system can be reversed so that chamber 11 'seryesas, the reaction chamber and chamber 10 serves as thecat-alyst scavenging bed. This is accomplished by opening valves 19, 34, 29 and 21 and closing valves 17, 30, 33 and 24. In this procedure, the catalyst system is effectively formed in-situ in the vessel which serves to remove catalyst residues from the reaction products. The desired product or products can be separated from other materials in the reactor efiiuent by fractionation or any other convenient procedure. I

'In'the procedure illustrated in the drawing, the vessel serving as the rea tor is maintained in the temperature range of 200 10 450 .F., preferably 300 to 400 F., with the pressure being in the range of 600 to 5000 p.s.i.g., preferab1yl500 to. 3500 p.s.i.g. The scavenging bed vessel is mai tained in the temperature range of 50 to 250 F, with the pressure being in the range of to 5000 p.s.i.g. The residence time in the scavenging bed vessel is generally in the range of seconds to 1 hour. Suitable heat exchangers and compressors, not shown, can be associated'with the illustrated apparatus to maintain these conditions.

The catalyst residue removal system can also be used to treat efiluent streams from conventional hydroformylation reactions employing any of the metals listed above as catalysts.

In another embodiment of this invention, p-styryldiethylphosphine is produced as a new compound. This phosphine can be produced by the procedure set forth hereinafter in Example II. In still another embodiment of this invention, solid polymers of p-styryldiethylphosphine are produced, as can be accomplished by the procedudre set forth in Example H.

The following examples demonstrate various features of this invention:

EXAMPLE I Solid, cross-linked, phosphorus-containing polymer was prepared through the use of p-styryldiphenylphosphine as a monomer.

To prepare the p-styryldiphenylphosphine, 0.1 mole of p-chlorostyrene was added to 0.1 gram-atom of magnesium in 50 ml. of refluxing tetrahydrofuran in a nitrogen atmosphere. After formation of the Grignard was complete, 0.1 mole of diphenylchlorophosphine was added dropwise to the mixture at 0 C. Hydrolysis of the reaction mixture with ammonium chloride solution, extraction with tetrahydrofuran, drying, and evaporation of the solvent left a yellow oil. Crystallization from hexane gave 14.5 grams of product melting at 71-75 C. Combination of several preparations and crystallization from hexane gave p-styryldiphenylphosphine, used subsequently for polymerization, as a white crystalline solid melting at 76-78 C Analysisr-calcdfor CgoH PI C, 83.3%; H, 5.94%, P 10.7%. Found: C, 82.8%; H, 6.0%; P, 10.87%.

grams of light yellow polymer, Polymer B. Analysis.- Found: C, 84.1%; H, 6.9%; P, 8.8%.

Table I summarizes the results obtained in a series of runs in which Polymer A or Polymer B was employed in a 300-ml. autoclave used to convert 2-hexene to normal and branched C aldehydes and normal and branched C alcohols in an oxo reaction carried out as a batch process. In each run an equimolar mixture of carbon monoxide and hydrogen at a total pressure of 1500-3300 p.s.i.g. at operating temperature was used. The initial run was made using 3 grams of the above Polymer A, 50 ml. of cyclohexane, 25 ml. of Z-hexene, and 3 ml. of a benzene solution of 0.42 gram of dicobalt octacarbonyl. In each of Runs 2 and 3, after decanting the products of the preceding run from the polymer, 50 m1. of cyclohexane and 25 ml. of 2-hexene were added, and the autoclave each time was repressured with carbon monoxide and hydrogen. In each of Runs 4, '5, and 6, after decanting the products of the preceding run from the polymer, 75 ml. of 2-hexene was added, and the autoclave each time was repressured with carbon monoxide and hydrogen. For Run 7 the polymer was replaced with another 3-gram portion of Polymer A, and 75 ml. of 2-hexene and 1 ml. of a benzene solution of 0.14 gram of dicobalt octacarbonyl were added prior to pressuring with carbon monoxide and hydrogen. In Run 8, after decanting the products of Run 7 from the polymer, 75 ml. of 2-hexene was added prior to repressuring with carbon monoxide and hydrogen. For Run 9 the polymer was replaced with 3 grams of Polymer B, and 75 ml. of 2-hexene and 1 ml. of a benzene solution of 0.14 gram of dicobalt octacarbonyl were added prior to pressuring with carbon monoxide and hydrogen. In each of Runs 10 and 11, after decanting the products of the preceding run from the polymer, 75 ml. of Z-hexene was added prior to repressuring with carbon monoxide and hydrogen. In each of the runs in Table I the conversion of 2-hexene was greater than 90 percent.

TABLE I Weight ratio of products 00 in Alcohol Aldehyde Temp., Time, efiluent,

Run 13. hrs. p.p.m. Normal Branched Normal Branched 1 250 1. 5 570 Trace Trace 67 33 2 350-400 -2 21 14 34 31 3 .350 2 18 10 6 47 37 4. 350 4 15 9 5 43 43 5. 320-350 5 21 8 6 42 44 6. 350-360 4. 5 7 7 5 43 54 7. 36 4 4 3 34 8. 380-400 6 13 8 38 14 9 380-400 4 33 23 24 02 10 370-380 4 9 8 42 14 11 370-380 5 14 9 37 4 p Not determined.

The above monomer was used to prepare two batches of solid, cross-linked, phosphorus-containing polymer herein designated as Polymer A and Polymer B. Y

In the preparation of Polymer A, a mixture of 10 grams of p-styryldiphenylphosphine, 1 gram of a commercial mixture of 50 weight percent isomeric divinylbenzenes, 0.3 gram of 2,2'-azobis(2-methylpropionitrile), and 50 ml. of benzene was refluxed for 10 hours in a nitrogen atmosphere. The polymer was precipitated by pouring the reaction mixture slowly into methanol. Washing the precipitate with hexane, pentane, 'andether gave 11 grams. of freefiowing white polymenPolyIner A, softening at about.

The results of these runs demonstrate that cobalt-containing, solid, cross-linked polymers derived from p-styryldiphenylphosphine can be used repeatedly in an oxo reaction without further addition of cobalt catalyst. The ability of the polymer to bind the cobalt is also demonstrated.

EXAMPLE II p-Styryldiethylphosphine was prepared by adding 0.145

mole of diethylchlorophosphine to the Grignard reagent at 0 C. formed from 0.16 mole of p-chlorostyrene and 0.18 gram-atom of magnesium in 50 ml. of tetrahydrofuran in a nitrogen atmosphere. Hydrolysis with aqueous ammonium chloride, extraction with tetrahydrofuran, drying and distillation gave 8.3 grams of p-styryldiethylphosphine boiling at 81-83 C. at 0.1-0.15 mm. Hg. Analysis.- Calculated for C12H17PZ C, 75.0%; H, 8.85%. Found: C, 73.7%; H, 9.2%. Gas chromatographic analysis indicated the purity of the product to be greater than 99 weight percent, and the infrared and nuclear magnetic resonance spectra were consistent with those to be expected for a compound of the assigned structure, as set forth in detail hereinafter in Example III.

To prepare a solid, cross-linked, phosphorus-containing polymer, 7.8 grams of p-styryldiethylphosphine, 3 grams of a commercial mixture of 50 weight percent isomeric divinylbenzenes, and 1.5 grams of 2,2'-azobis(2-methylpropionitrile) were heated in 50 ml. of benzene at reflux for 10 hours in a nitrogen atmosphere. Evaporation of the benzene, washing of the residue with hexane, and drying gave 10.7 grams of free-flowing, light yellow, solid, crosslinked polymer of p-styryldiethylphosphine. A11alysis. Found: C, 73.3%;I-I, 8.8%.

Table II summarizes the results obtained in a series of runs in which the above polymer of p-styryldiethylphosphine was employed in a BOO-ml. autoclave used to pre pare normal and branched C aldehydes and normal and branched C alcohols from Z-hexene in an oxo reaction carried out as a batch process. In each run an aquimolar mixture of carbon monoxide and hydrogen at a total pres- The infrared spectrum obtained is illustrated in FIG. 2 of the drawing. The observed absorption bands represent the following structure:

Structure 0-H stretch. C=C stretch (from vinyl group). 0-H bending modes.

Band (microns) The nuclear magnetic resonance (NMR) data show a structural formula as follows:

r CH

N o. of protons ex- Chemical pen'mentally shift position Multlphclty Assignment found H 2.37-2.83 tau- Disturbed singlet- Aromatic n'ng protons. 4. o H 3.00-3.58 tau. Quartet of singlets- Non-terminal olefinic proton in a vinyl group 0. 9 H and E 4.03-4.97 tau- Two quartets Two non-equivalent tenninal olefinic protons in vinyl groupl. 9 11 Do Methylene alpha toP 4.1 Methyl bet-a to-P 6. 1

Conjugation within the styryl part of the molecule is thought to maintain the vinyl group and the benzene ring in the same plane. This produces a non-equivalence in the aromatic ring protons resulting in the disturbed appearance of the aromatic resonance, H

1 The protons making up the vinyl group (H H, H give a characteristic ABC resonance whose fine structure is determined by 3 different chemical shifts (v) and 3 coupling constants (I).

TABLE H Weight ratio of products Go in Alcohol Aldehyde Temp Time, etfiuent, Run hr p.p.m. Normal Branched Normal Branched The results of these runs demonstrate that a cobalt- 5 vH =3.3 tau containing, solid, cross-linked polymer derived from p styryldiethylphosphine can be used repeatedly in an oxo reaction without further addition of cobalt catalyst. Also demonstrated is the ability of the polymer to bind the I cobalt.

EXAMPLE III The material produced in Example II was identified as p-styryldiethylphosphine by infrared and nuclear magnetic resonance measurements.

1 =10.5 c.p.s. vH" =4.8 tau J =17.5 c.p.s. vH =4.3 tau J =1.5 c.p.s.

The hydrogennuclei of the vinyl group in the styryl part of the molecule are observed to give anomalous chemical shifts. This is due largely to the effects of diamagnetic circulations of electrons in the aromatic ring (ring currents). Banwell and Sheppard, Molec. Phy., 3, 351 (1960), have estimated the necessary corrections to the vinyl chemical shifts for these ring currents. By applying these corrections the resulting chemical shifts were found to be correct for the styryl group.

The chemical shifts of the alkyl groups (H and H) are downfield from their normal positions due to the electronegativity of the phosphorus atom. This part of the spectrum may be considered as a typical A B system. The l -P coupling constant is 1 c.p.s., which shows that for the alkyl methylenes two quartets are superimposed. The J P coupling is known (Emsley et 211., High Resolution NMR Spectroscopy, 1, 1966, Pergamon Press, p. 372) to be large and in this sample is found to be about c.p.s., so that 2 overlapping triplets for the methyl group resonances are obtained.

While this invention has been described in conjunction with presently preferred embodiments, it obviously is not limited thereto.

What is claimed is:

1. In a hydroformylation process in which an olefin is reacted with carbon monoxide and hydrogen under hydroformylation conditions; the improvement which comprises carrying out the reaction under hydroformylation conditions in the presence of a catalyst produced by contacting a solid phosphorus-containing polymer of at least one phosphine of the formula wherein each R is hydrogen or an alkyl group having 1 to 4 carbon atoms, the total number of carbon atoms in all of the R substituents being 12 or less, each R is a hydrocarbyl radical selected from alkyl, cycloalkyl, aryl and combinations thereof, said hydrocarbyl radical containing 1 to carbon atoms, and n is 1 to 3, with at least one metal carbonyl of the group consisting of cobalt, rhodium, ruthenium, platinum and palladium, said metal being present in an amount in the range of 0.2 to 20 millimoles of metal per 5 grams of polymer support.

2. The process of claim 1 wherein said metal is cobalt and is associated with said polymer as cobalt hydrocarbonyl or dicobalt octacarbonyl.

3. The process of claim 10 wherein said polymer is a polymer prepared by polymerizing said phosphine in the presence of from about 1 to 40 parts by weight per 100 parts of phosphine of at least one vinyl aromatic compound of the formula 4. The process of claim 3 wherein said vinyl aromatic compound is divinylbenzene.

5. The process of claim 10 wherein said reaction is carred out by passing the olefin carbon monoxide and hydrogen through a first zone containing said catalyst, and further comprising the step of passing the efiluent from said first zone through a second zone which contains 10 a solid phosphorus-containingpolymer of at least one phosphine of the formula (CH=CH2) 1:

6. The process of claim 5 wherein the passage of materials through said first and second zones is discontinued after a selected time and thereafter olefinic material, carbon monoxide and hydrogen are passed through said sec ond zone and the effluent therefrom is passed through said first zone.

7. In a hydroformylation process in which an olefin is reacted in a first zone with carbon monoxide and hydrogen under hydroformylation conditions in the presence of a catalyst containing at least one metal selected from the group consisting of cobalt, rhodium, ruthenium, platinum and palladium, the method of recovering catalyst residues which comprises passing the effluent from said first zone through a second zone which contains a solid phosphoruscontaining polymer of at least one phosphine of the formula phosphine of at least one polyvinyl aromatic compound of the formula (CH CH)n R (ii-n) or or (CH2: 0H)n (CH2: CH) R (10-u 9. The process of claim 5 wherein the solid polymer in the first zone is confined therein by positioning screens across the inlet and outlet of said first zone and the solid polymer in the second zone is confined therein by positioning screens across the inlet and outlet of the second zone.

10. The process of claim 1 wherein the reaction is carried out in the pressure range of 600 to 5,000 p.s.i.g. and in the temperature range of 200 to 450 F.

11. The process of claim 6 wherein the pressure in the second zone is maintained in the range of 600 to 5,000 p.s.i.g. and the temperature of the second zone is maintained in the range of 200 to 450 F. during the time that olefinic material, carbon monoxide and hydrogen are passed through the second zone and the eflluent therefrom is passed through the first zone.

12. The process of claim 1 wherein said reaction is carried out by passing the olefinic material, carbon monoxide and hydrogen through a first zone containing said catalyst, and further comprising the step of passing the effiuent from said first zone through a second zone which contains a solid phosphorus-containing polymer of at least one phosphine of the formula G-n) (References on following page) References Cited UNITED STATES PATENTS Tyurenkova et a1.: Chem. Abstracts, vol. 60, 1964, col.

Eggs? %2 Z Allan et aL: Journ. of Catalysis, vol. 19', 1970, pp. 12/1969 Paulik et a1 260-604 HF 5 2 1 V1972 Solomon 260 604 HF ais ey et al.. Journ. of P0 ymer Science, vol. 56, pp.

533-538, 1962. FOREIGN PATENTS France T- Primary Examiner 6/ 1962 Germany 260604 HF 10 R. H. LILES, Assistant Examiner 2/1961 Germany 260--604 HF 4/1965 Great Britain 260604 HF U.S. Cl. X.R.

2/ 1965 Great Britain 260604 X OTHER REFERENCES 252431 P; 260-638 HF 

1. IN A HYDROFORMYLATION PROCESS IN WHICH AN OLEFIN IS REACTED WITH CARBON MONOXIDE AND HYDROGEN UNDER HYDROFORMYLATION CONDITIONS; THE IMPROVEMENT WHICH COMPRISES CARYING OUT THE REACTION UNDER HYDROFORMYLATION CONDITIONS IN THE PRESENCE OF A CATALYST PRODUCED BY CONTACTING A SOLID PHOSPHORUS-CONTAINING POLYMER OF AT LEAST ONE PHOSPHINE OF THE FORMULA 